Properties of hydrocarbons

Lajoy Tucker

Teacher

Lajoy Tucker

Properties of hydrocarbons

Hydrocarbons are compounds made of hydrogen and carbon atoms only.

Their properties depend on the length of their carbon chains – that is, the size of their molecules.

Property

Definition

Trend with Increasing Molecular Size (Chain Length)

Boiling point

The temperature at which a substance changes from liquid to gas

Increases – larger molecules have stronger intermolecular forces and need more energy to evaporate

Viscosity

How thick or sticky a liquid is

Increases – longer chains make the liquid flow more slowly

Flammability

How easily a substance burns

Decreases – larger molecules are harder to ignite and burn less cleanly

How These Properties Affect Fuel Use

Typical Use

Reason

Short-chain hydrocarbons (e.g. refinery gases, petrol)

Fuels for cooking, heating, and vehicles

Burn easily and cleanly, gases at room temperature

Long-chain hydrocarbons (e.g. heavy oils, bitumen)

Lubricants, ship fuels, road surfacing

Viscous, hard to burn, high boiling points

Check for Understanding

Recall

a) What elements are in hydrocarbons?

Answer

Carbon and hydrogen only.

b) How does boiling point change with chain length?

Answer

Increases.

c) How does viscosity change with chain length?

Answer

Increases.

d. What happens to volatility as chain length increases?

Answer

Decreases.

Application

e) Explain why short-chain hydrocarbons are more flammable.

Answer

Smaller molecules with relatively weak intermolecular forces; Lower boiling point; ignite easily.

f) Explain why long-chain hydrocarbons are less useful as fuels.

Answer

Larger molecules with relatively stronger weak intermolecular forces (compared to short cains); Harder to ignite; high boiling point; viscous.

g) Explain why boiling point increases as molecular size increases.

Answer

Larger molecules; stronger intermolecular forces; more energy needed to overcome them.

Summary

  • Hydrocarbon properties depend on molecular size.

  • Larger molecules → higher boiling points, more viscous, less flammable.

  • Short-chain hydrocarbons are best as fuels

No answer provided.